The Alternate Exterior Angles Theorem states that, when two parallel lines are cut by a transversal, the resulting alternate exterior angles are congruent.
So, in the figure below, if k || l, then
1
7
and
4
6.

Proof.
Since l || m, by the Corresponding Angles Postulate,
1
5.
Also, by the Vertical Angles Theorem,
5
7.
Then, by the Transitive Property of Congruence,
1
7.
You can prove that
4 and
6 are congruent using the same method.
The converse of this theorem is also true; that is, if two lines k and l are cut by a transversal so that the alternate exterior angles are congruent, then k || l.